Proton tunneling estimates for malonaldehyde vibrations from supersonic jet and matrix quenching experiments

FTIR tunneling splittings for a range of fundamental excitations of malonaldehyde are determined from adiabatic cooling and symmetry breaking experiments in three different molecular states (isolated, coated by Ar layers and embedded in bulk Ar matrices), showing that there is room for improvement i...

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2006-05, Vol.8 (20), p.2344-2348
Main Authors: WASSERMANN, T. N, LUCKHAUS, D, COUSSAN, S, SUHM, M. A
Format: Article
Language:English
Subjects:
Chemistry
Computer Simulation
Exact sciences and technology
Gases - chemistry
General and physical chemistry
Malondialdehyde - analysis
Malondialdehyde - chemistry
Models, Chemical
Protons
Semiconductors
Spectroscopy, Fourier Transform Infrared - methods
Vibration
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Summary:FTIR tunneling splittings for a range of fundamental excitations of malonaldehyde are determined from adiabatic cooling and symmetry breaking experiments in three different molecular states (isolated, coated by Ar layers and embedded in bulk Ar matrices), showing that there is room for improvement in available theoretical models.
ISSN:1463-9076
1463-9084
DOI:10.1039/b602319n