Copper(II) and Zinc(II) Complexes Can Fix Atmospheric Carbon Dioxide

Carbonato bridges from atmospheric carbon dioxide: The copper(II) and zinc(II) complexes of the novel imidazole‐containing polyamine ligand N1‐(2‐aminoethyl)‐N1‐(2‐imidazolethyl)ethane‐1,2‐diamine are found to fix carbon dioxide by hydration to μ3‐carbonate ligands. This is revealed by IR and solid‐...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2005-07, Vol.44 (28), p.4352-4355
Main Authors: Kong, Ling-Yan, Zhang, Zheng-Hua, Zhu, Hui-Fang, Kawaguchi, Hiroyuki, Okamura, Taka-aki, Doi, Mototsugu, Chu, Qian, Sun, Wei-Yin, Ueyama, Norikazu
Format: Article
Language:English
Subjects:
Atmosphere - chemistry
Carbon Dioxide - chemistry
Carbon Dioxide - metabolism
carbon dioxide fixation
copper
Copper - chemistry
Ligands
Macromolecular Substances - chemistry
Magnetic Resonance Spectroscopy
Models, Molecular
networks
NMR spectroscopy
zinc
Zinc - chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Carbonato bridges from atmospheric carbon dioxide: The copper(II) and zinc(II) complexes of the novel imidazole‐containing polyamine ligand N1‐(2‐aminoethyl)‐N1‐(2‐imidazolethyl)ethane‐1,2‐diamine are found to fix carbon dioxide by hydration to μ3‐carbonate ligands. This is revealed by IR and solid‐state 13C NMR spectroscopic and X‐ray crystallographic studies of the two‐dimensional complexes (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200500587