Synthesis and Characterization of [PhC(NtBu)2]SiCl: A Stable Monomeric Chlorosilylene

The single life: The reaction of [PhC(NtBu)2]SiCl3 (1) with potassium afforded the monomeric chlorosilylene [PhC(NtBu)2]SiCl (2). The X‐ray crystal structure of 2 has been determined and natural‐bond‐orbital analysis carried out.

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2006-06, Vol.45 (24), p.3948-3950
Main Authors: So, Cheuk-Wai, Roesky, Herbert W., Magull, Jörg, Oswald, Rainer B.
Format: Article
Language:English
Subjects:
carbene homologues
halides
N ligands
silicon
silylenes
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Summary:The single life: The reaction of [PhC(NtBu)2]SiCl3 (1) with potassium afforded the monomeric chlorosilylene [PhC(NtBu)2]SiCl (2). The X‐ray crystal structure of 2 has been determined and natural‐bond‐orbital analysis carried out.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200600647