Strategies for Hydrogen Storage in Metal-Organic Frameworks

Increased attention is being focused on metal–organic frameworks as candidates for hydrogen storage materials. This is a result of their many favorable attributes, such as high porosity, reproducible and facile syntheses, amenability to scale‐up, and chemical modification for targeting desired prope...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2005-07, Vol.44 (30), p.4670-4679
Main Authors: Rowsell, Jesse L. C., Yaghi, Omar M.
Format: Article
Language:English
Subjects:
adsorption
hydrogen
metal-organic frameworks
microporous materials
organic-inorganic hybrid composites
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c4876-e78a46e691def725b9d1c92bc06c57385939e358b853e099d9830367d84edd073
cites cdi_FETCH-LOGICAL-c4876-e78a46e691def725b9d1c92bc06c57385939e358b853e099d9830367d84edd073
container_end_page 4679
container_issue 30
container_start_page 4670
container_title Angewandte Chemie International Edition
container_volume 44
creator Rowsell, Jesse L. C.
Yaghi, Omar M.
description Increased attention is being focused on metal–organic frameworks as candidates for hydrogen storage materials. This is a result of their many favorable attributes, such as high porosity, reproducible and facile syntheses, amenability to scale‐up, and chemical modification for targeting desired properties. A discussion of several strategies aimed at improving hydrogen uptake in these materials is presented. These strategies include the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals. Reaching a compromise: Metal–organic frameworks such as MOF‐177 (see picture) are potential hydrogen‐storage materials, but the pores (yellow sphere) are much larger than the molecular diameter of H2, thus limiting their effectiveness. Their hydrogen uptake may be improved by impregnation with other moieties (such as C60, gray) to provide additional adsorptive sites and stronger H2 binding at the expense of high porosity.
doi_str_mv 10.1002/anie.200462786
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68074909</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>68074909</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4876-e78a46e691def725b9d1c92bc06c57385939e358b853e099d9830367d84edd073</originalsourceid><addsrcrecordid>eNqFkEtPwkAUhSdGI4huXZqu3BVnOu084goIL4MQReNyMm1vm0pLcaYE-feWlKA7V_csvvPd5CB0S3CXYOw96HUGXQ9jn3lcsDPUJoFHXMo5Pa-zT6nLRUBa6Mraz5oXArNL1CKsjh7mbfS4rIyuIM3AOklpnMk-NmUKa2dZlUan4GRr5xkqnbsLk9bPImdkdAG70qzsNbpIdG7h5ng76H00fBtM3NliPB30Zm7kC85c4EL7DJgkMSTcC0IZk0h6YYRZFHAqAkkl0ECEIqCApYyloJgyHgsf4hhz2kH3jXdjyq8t2EoVmY0gz_Uayq1VTGDuSyxrsNuAkSmtNZCojckKbfaKYHWYSx3mUqe56sLd0bwNC4h_8eM-NSAbYJflsP9Hp3rz6fCv3G26ma3g-9TVZqUYpzxQH_OxotR_8l76ffVKfwCJD4R4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68074909</pqid></control><display><type>article</type><title>Strategies for Hydrogen Storage in Metal-Organic Frameworks</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Rowsell, Jesse L. C. ; Yaghi, Omar M.</creator><creatorcontrib>Rowsell, Jesse L. C. ; Yaghi, Omar M.</creatorcontrib><description>Increased attention is being focused on metal–organic frameworks as candidates for hydrogen storage materials. This is a result of their many favorable attributes, such as high porosity, reproducible and facile syntheses, amenability to scale‐up, and chemical modification for targeting desired properties. A discussion of several strategies aimed at improving hydrogen uptake in these materials is presented. These strategies include the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals. Reaching a compromise: Metal–organic frameworks such as MOF‐177 (see picture) are potential hydrogen‐storage materials, but the pores (yellow sphere) are much larger than the molecular diameter of H2, thus limiting their effectiveness. Their hydrogen uptake may be improved by impregnation with other moieties (such as C60, gray) to provide additional adsorptive sites and stronger H2 binding at the expense of high porosity.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.200462786</identifier><identifier>PMID: 16028207</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>adsorption ; hydrogen ; metal-organic frameworks ; microporous materials ; organic-inorganic hybrid composites</subject><ispartof>Angewandte Chemie International Edition, 2005-07, Vol.44 (30), p.4670-4679</ispartof><rights>Copyright © 2005 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4876-e78a46e691def725b9d1c92bc06c57385939e358b853e099d9830367d84edd073</citedby><cites>FETCH-LOGICAL-c4876-e78a46e691def725b9d1c92bc06c57385939e358b853e099d9830367d84edd073</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16028207$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rowsell, Jesse L. C.</creatorcontrib><creatorcontrib>Yaghi, Omar M.</creatorcontrib><title>Strategies for Hydrogen Storage in Metal-Organic Frameworks</title><title>Angewandte Chemie International Edition</title><addtitle>Angewandte Chemie International Edition</addtitle><description>Increased attention is being focused on metal–organic frameworks as candidates for hydrogen storage materials. This is a result of their many favorable attributes, such as high porosity, reproducible and facile syntheses, amenability to scale‐up, and chemical modification for targeting desired properties. A discussion of several strategies aimed at improving hydrogen uptake in these materials is presented. These strategies include the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals. Reaching a compromise: Metal–organic frameworks such as MOF‐177 (see picture) are potential hydrogen‐storage materials, but the pores (yellow sphere) are much larger than the molecular diameter of H2, thus limiting their effectiveness. Their hydrogen uptake may be improved by impregnation with other moieties (such as C60, gray) to provide additional adsorptive sites and stronger H2 binding at the expense of high porosity.</description><subject>adsorption</subject><subject>hydrogen</subject><subject>metal-organic frameworks</subject><subject>microporous materials</subject><subject>organic-inorganic hybrid composites</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPwkAUhSdGI4huXZqu3BVnOu084goIL4MQReNyMm1vm0pLcaYE-feWlKA7V_csvvPd5CB0S3CXYOw96HUGXQ9jn3lcsDPUJoFHXMo5Pa-zT6nLRUBa6Mraz5oXArNL1CKsjh7mbfS4rIyuIM3AOklpnMk-NmUKa2dZlUan4GRr5xkqnbsLk9bPImdkdAG70qzsNbpIdG7h5ng76H00fBtM3NliPB30Zm7kC85c4EL7DJgkMSTcC0IZk0h6YYRZFHAqAkkl0ECEIqCApYyloJgyHgsf4hhz2kH3jXdjyq8t2EoVmY0gz_Uayq1VTGDuSyxrsNuAkSmtNZCojckKbfaKYHWYSx3mUqe56sLd0bwNC4h_8eM-NSAbYJflsP9Hp3rz6fCv3G26ma3g-9TVZqUYpzxQH_OxotR_8l76ffVKfwCJD4R4</recordid><startdate>20050725</startdate><enddate>20050725</enddate><creator>Rowsell, Jesse L. C.</creator><creator>Yaghi, Omar M.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20050725</creationdate><title>Strategies for Hydrogen Storage in Metal-Organic Frameworks</title><author>Rowsell, Jesse L. C. ; Yaghi, Omar M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4876-e78a46e691def725b9d1c92bc06c57385939e358b853e099d9830367d84edd073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>adsorption</topic><topic>hydrogen</topic><topic>metal-organic frameworks</topic><topic>microporous materials</topic><topic>organic-inorganic hybrid composites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rowsell, Jesse L. C.</creatorcontrib><creatorcontrib>Yaghi, Omar M.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rowsell, Jesse L. C.</au><au>Yaghi, Omar M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Strategies for Hydrogen Storage in Metal-Organic Frameworks</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angewandte Chemie International Edition</addtitle><date>2005-07-25</date><risdate>2005</risdate><volume>44</volume><issue>30</issue><spage>4670</spage><epage>4679</epage><pages>4670-4679</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Increased attention is being focused on metal–organic frameworks as candidates for hydrogen storage materials. This is a result of their many favorable attributes, such as high porosity, reproducible and facile syntheses, amenability to scale‐up, and chemical modification for targeting desired properties. A discussion of several strategies aimed at improving hydrogen uptake in these materials is presented. These strategies include the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals. Reaching a compromise: Metal–organic frameworks such as MOF‐177 (see picture) are potential hydrogen‐storage materials, but the pores (yellow sphere) are much larger than the molecular diameter of H2, thus limiting their effectiveness. Their hydrogen uptake may be improved by impregnation with other moieties (such as C60, gray) to provide additional adsorptive sites and stronger H2 binding at the expense of high porosity.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>16028207</pmid><doi>10.1002/anie.200462786</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1433-7851
ispartof Angewandte Chemie International Edition, 2005-07, Vol.44 (30), p.4670-4679
issn 1433-7851
1521-3773
language eng
recordid cdi_proquest_miscellaneous_68074909
source Wiley-Blackwell Read & Publish Collection
subjects adsorption
hydrogen
metal-organic frameworks
microporous materials
organic-inorganic hybrid composites
title Strategies for Hydrogen Storage in Metal-Organic Frameworks
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T14%3A17%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Strategies%20for%20Hydrogen%20Storage%20in%20Metal-Organic%20Frameworks&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Rowsell,%20Jesse%20L.%20C.&rft.date=2005-07-25&rft.volume=44&rft.issue=30&rft.spage=4670&rft.epage=4679&rft.pages=4670-4679&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.200462786&rft_dat=%3Cproquest_cross%3E68074909%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c4876-e78a46e691def725b9d1c92bc06c57385939e358b853e099d9830367d84edd073%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=68074909&rft_id=info:pmid/16028207&rfr_iscdi=true