High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites

A copper‐based metal–organic framework (MOF) has been synthesized, and its structure has been solved by X‐ray crystallography (see picture; Cu blue, C black, O red, framework pore yellow). The remarkably high hydrogen adsorption properties (2.47 wt %) of this compound have been studied.

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2005-07, Vol.44 (30), p.4745-4749
Main Authors: Chen, Banglin, Ockwig, Nathan W., Millward, Andrew R., Contreras, Damacio S., Yaghi, Omar M.
Format: Article
Language:English
Subjects:
adsorption
copper
hydrogen
metal-organic frameworks
microporous materials
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Description
Summary:A copper‐based metal–organic framework (MOF) has been synthesized, and its structure has been solved by X‐ray crystallography (see picture; Cu blue, C black, O red, framework pore yellow). The remarkably high hydrogen adsorption properties (2.47 wt %) of this compound have been studied.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200462787