Thermodynamic Scales for Sulfur Atom Transfer and Oxo-for-Sulfido Exchange Reactions

Inner sphere two-electron redox processes as represented by chalcogenido and imido transfer reactions constitute one of the fundamental reaction types of transition metal chemistry. This paper addresses thermodynamic aspects of sulfur atom transfer and oxo-for-sulfido exchange reaction chiefly when...

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Bibliographic Details
Published in:Chemical reviews 2006-11, Vol.106 (11), p.4747-4783
Main Author: Donahue, James P
Format: Article
Language:English
Subjects:
Chemical reactions
Chemistry
Metals
Sulfur
Thermodynamics
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Summary:Inner sphere two-electron redox processes as represented by chalcogenido and imido transfer reactions constitute one of the fundamental reaction types of transition metal chemistry. This paper addresses thermodynamic aspects of sulfur atom transfer and oxo-for-sulfido exchange reaction chiefly when they involve transition metals.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr050044w