Optical Rotation of Achiral Pentaerythritol

The optical rotatory power of achiral crystals of achiral pentaerythritol molecules was measured. The maximum rotations were found to be ±6°/mm. The quantum mechanically computed rotation of pentaerythritol molecules using linear response theory was 6 times larger although the experimental and theor...

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Published in:Journal of the American Chemical Society 2006-11, Vol.128 (46), p.14746-14747
Main Authors: Claborn, Kacey, Herreros Cedres, Javier, Isborn, Christine, Zozulya, Alexey, Weckert, Edgar, Kaminsky, Werner, Kahr, Bart
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Chemistry
Exact sciences and technology
General and physical chemistry
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creator Claborn, Kacey
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Kahr, Bart
description The optical rotatory power of achiral crystals of achiral pentaerythritol molecules was measured. The maximum rotations were found to be ±6°/mm. The quantum mechanically computed rotation of pentaerythritol molecules using linear response theory was 6 times larger although the experimental and theoretical tensors were similarly oriented to within 5°.
doi_str_mv 10.1021/ja064631q
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subjects Chemistry
Exact sciences and technology
General and physical chemistry
title Optical Rotation of Achiral Pentaerythritol
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