Identification of hydrolysis products of FeCl3.6H2O by ESI-MS

The hydrolysis reactions of FeCl3 in 0.1 mM aqueous solutions were monitored by electrospray ionisation time-of-flight mass spectrometry (ESI-ToF-MS). In contrast to the other ionisation techniques, electrospray ionisation provides information on the composition of the elemental cores even in water...

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Published in:Journal of mass spectrometry. 2006-11, Vol.41 (11), p.1421-1429
Main Authors: Hellman, Heikki, Laitinen, Risto S, Kaila, Leena, Jalonen, Jorma, Hietapelto, Vesa, Jokela, Jukka, Sarpola, Arja, Rämö, Jaakko
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container_issue 11
container_start_page 1421
container_title Journal of mass spectrometry.
container_volume 41
creator Hellman, Heikki
Laitinen, Risto S
Kaila, Leena
Jalonen, Jorma
Hietapelto, Vesa
Jokela, Jukka
Sarpola, Arja
Rämö, Jaakko
description The hydrolysis reactions of FeCl3 in 0.1 mM aqueous solutions were monitored by electrospray ionisation time-of-flight mass spectrometry (ESI-ToF-MS). In contrast to the other ionisation techniques, electrospray ionisation provides information on the composition of the elemental cores even in water and salt cluster ions. Therefore, the technique facilitates detection of the bonding of the chloride ions in the oxo-hydroxo-iron cores. A variety of mononuclear and polynuclear iron-oxohydroxo-chloride complexes were characterised from the cationic and anionic mass spectra of iron(III) solutions. Oxidation and reduction reactions of iron, as well as competition between OH- and Cl- ions within one iron core, were also observed.
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title Identification of hydrolysis products of FeCl3.6H2O by ESI-MS
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