Monohelical Iron(II) and Zinc(II) Complexes of a (1R,2R)-Cyclohexyl Salen Ligand with Benz[a]anthryl Sidearms

An enantiomerically pure C 2-symmetric salen ligand with benz[a]anthracene siderams produces M helical complexes (FeII and ZnII) in solution. Interconversion to produce a 1:1 mixture of helical conformers in the solid state is possible, despite overlapped sidearms.

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Published in:Inorganic chemistry 2006-12, Vol.45 (25), p.10034-10036
Main Authors: Wiznycia, Alexander V, Desper, John, Levy, Christopher J
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Language:English
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cited_by cdi_FETCH-LOGICAL-a351t-72371ee8710112d80a06c785a3412c1222e79b3835555aa03914a6e362e81f383
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description An enantiomerically pure C 2-symmetric salen ligand with benz[a]anthracene siderams produces M helical complexes (FeII and ZnII) in solution. Interconversion to produce a 1:1 mixture of helical conformers in the solid state is possible, despite overlapped sidearms.
doi_str_mv 10.1021/ic061553z
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title Monohelical Iron(II) and Zinc(II) Complexes of a (1R,2R)-Cyclohexyl Salen Ligand with Benz[a]anthryl Sidearms
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