Spin Transition in a Chainlike Supramolecular Iron(II) Complex

A one-dimensional supramolecular head-to-tail N+−H···N-type hydrogen-bonded chain of the complex [FeII(L)2H](ClO4)3·MeOH [L = 4‘-(4‘ ‘‘-pyridyl)-1,2‘:6‘1‘ ‘-bis(pyrazolyl)pyridine] exhibits a reversible, thermally driven spin transition at 286 K with a hysteresis loop of ca. 2 K....

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Bibliographic Details
Published in:Inorganic chemistry 2006-12, Vol.45 (25), p.10019-10021
Main Authors: Rajadurai, Chandrasekar, Schramm, Frank, Brink, Susan, Fuhr, Olaf, Ghafari, Mohamed, Kruk, Robert, Ruben, Mario
Format: Article
Language:English
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Summary:A one-dimensional supramolecular head-to-tail N+−H···N-type hydrogen-bonded chain of the complex [FeII(L)2H](ClO4)3·MeOH [L = 4‘-(4‘ ‘‘-pyridyl)-1,2‘:6‘1‘ ‘-bis(pyrazolyl)pyridine] exhibits a reversible, thermally driven spin transition at 286 K with a hysteresis loop of ca. 2 K.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic0612350