Relativistic Functional Groups: Aryl Carbon-Gold Bond Formation by Selective Transmetalation of Boronic Acids

Gilded organometallics: Carbon–gold bond formation occurs selectively and in high yields upon reaction of gold(I) bromides with arylboronic acids in the presence of Cs2CO3. The reaction is broadly tolerant of sensitive functionalities. The resulting aryl gold(I) compounds are stable to air and water...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2006-12, Vol.45 (48), p.8188-8191
Main Authors: Partyka, David V., Zeller, Matthias, Hunter, Allen D., Gray, Thomas G.
Format: Article
Language:English
Subjects:
boron
Boronic Acids - chemistry
gold
Gold - chemistry
Models, Molecular
Molecular Structure
phosphane ligands
photodynamic therapy
transmetalation
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Summary:Gilded organometallics: Carbon–gold bond formation occurs selectively and in high yields upon reaction of gold(I) bromides with arylboronic acids in the presence of Cs2CO3. The reaction is broadly tolerant of sensitive functionalities. The resulting aryl gold(I) compounds are stable to air and water.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200603350