Facile Synthesis of Well-Defined Block Copolymers Containing Regioregular Poly(3-hexyl thiophene) via Anionic Macroinitiation Method and Their Self-Assembly Behavior

P3HT-P2VP block copolymers were synthesized using anionic macroinitiation of a vinyl end-functionalized P3HT. With different block ratio of P2VP to P3HT, the block copolymers exhibit sphere, cylinder, lamellae, and nanofiber nanostructures.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2007-09, Vol.129 (36), p.11036-11038
Main Authors: Dai, Chi-An, Yen, Wei-Che, Lee, Yi-Huan, Ho, Chun-Chi, Su, Wei-Fang
Format: Article
Language:English
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Description
Summary:P3HT-P2VP block copolymers were synthesized using anionic macroinitiation of a vinyl end-functionalized P3HT. With different block ratio of P2VP to P3HT, the block copolymers exhibit sphere, cylinder, lamellae, and nanofiber nanostructures.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0733991