A New Copper(II) Complex as an Efficient Catalyst of Luminol Chemiluminescence

A new copper complex (2) has exhibited highly efficient catalytic activity of luminol chemiluminescence in water in the presence of ascorbic acid and dissolved O2 under conditions that conventional catalysts such as Cu(OAc)2, hemin or cyclen−Cu(II) did not show significant activity.

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Bibliographic Details
Published in:Organic letters 2007-10, Vol.9 (21), p.4383-4386
Main Authors: Uzu, Takahiro, Sasaki, Shigeki
Format: Article
Language:English
Subjects:
Ascorbic Acid - chemistry
Catalysis
Copper - chemistry
Luminescent Measurements
Luminol - chemistry
Organometallic Compounds - chemistry
Oxygen - chemistry
Water - chemistry
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Description
Summary:A new copper complex (2) has exhibited highly efficient catalytic activity of luminol chemiluminescence in water in the presence of ascorbic acid and dissolved O2 under conditions that conventional catalysts such as Cu(OAc)2, hemin or cyclen−Cu(II) did not show significant activity.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol702002e