Dual role of azide in the formation of a 3D coordination polymer containing bridging 5-pyrimidinecarboxylate

A new 3D framework [Mn4(5-pmc)4(1,1-N3)4]n () composed of a rare MnII4 square as the repeating secondary building unit, representing the first coordination polymer of 5-pyrimidinecarboxylate (5-pmc) has been successfully synthesized and characterized by X-ray single crystal structure analysis.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2007-01 (40), p.4514-4516
Main Authors: Sengupta, Oindrila, Chakrabarty, Rajesh, Mukherjee, Partha Sarathi
Format: Article
Language:English
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Summary:A new 3D framework [Mn4(5-pmc)4(1,1-N3)4]n () composed of a rare MnII4 square as the repeating secondary building unit, representing the first coordination polymer of 5-pyrimidinecarboxylate (5-pmc) has been successfully synthesized and characterized by X-ray single crystal structure analysis.
ISSN:1477-9226
1477-9234
DOI:10.1039/b711346c