Conversion of indanone oximes into isocarbostyrils

New and effective method for the Beckmann rearrangement of indanone oxime mesylate is described, in which a selective and controlled production of the isomeric isocarbostyrils is achieved.

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Bibliographic Details
Published in:Bioorganic & medicinal chemistry letters 2007-01, Vol.17 (2), p.453-455
Main Authors: Torisawa, Yasuhiro, Aki, Shinji, Minamikawa, Jun-ichi
Format: Article
Language:English
Subjects:
Beckmann rearrangement
Chemistry
CPME
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with only one n hetero atom and condensed derivatives
Indanone
Indicators and Reagents
Isocarbostyril
Isomerism
Isoquinolines - chemical synthesis
Mesylates - chemistry
Organic chemistry
Oxime
Oximes - chemistry
Preparations and properties
Solvents
Titanium - chemistry
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Description
Summary:New and effective method for the Beckmann rearrangement of indanone oxime mesylate is described, in which a selective and controlled production of the isomeric isocarbostyrils is achieved.
ISSN:0960-894X
1464-3405
DOI:10.1016/j.bmcl.2006.10.022