Conjugated Microporous Poly(aryleneethynylene) Networks

Rigid wiry nets: Conjugated microporous polymer networks are formed by Sonogashira–Hagihara coupling. Although these materials are amorphous, the micropore size and surface area can be controlled by varying the length of the phenyleneethynylene struts (see picture; the network is shown in blue, and...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (45), p.8574-8578
Main Authors: Jiang, Jia-Xing, Su, Fabing, Trewin, Abbie, Wood, Colin D, Campbell, Neil L, Niu, Hongjun, Dickinson, Calum, Ganin, Alexey Y, Rosseinsky, Matthew J, Khimyak, Yaroslav Z, Cooper, Andrew I
Format: Article
Language:English
Subjects:
Amorphous materials
Benzene
conjugation
Joining
microporous materials
Networks
Pictures
polymerization
Struts
Surface area
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Summary:Rigid wiry nets: Conjugated microporous polymer networks are formed by Sonogashira–Hagihara coupling. Although these materials are amorphous, the micropore size and surface area can be controlled by varying the length of the phenyleneethynylene struts (see picture; the network is shown in blue, and one 1,3,5‐substituted benzene node and three connected struts are highlighted with C gray and H white).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200701595