Tandem Catalysis for a One-Pot Regioselective Protection of Carbohydrates: The Example of Glucose

Fine‐tuning the conditions for a tandem reaction using a single catalyst in a single reaction vessel leads to carbohydrate building blocks displaying different patterns of protecting groups (see picture). This process greatly simplifies the access to oligomers, as illustrated by the rapid assembly o...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (45), p.8662-8665
Main Authors: Français, Antoine, Urban, Dominique, Beau, Jean-Marie
Format: Article
Language:English
Subjects:
Assembly
Carbohydrates
Carbohydrates - chemistry
Catalysis
Catalysts
Copper - chemistry
Glucose
Glucose - chemistry
Lewis acids
Metals - chemistry
Molecular Conformation
Molecular Structure
Oligomers
Pictures
regioselectivity
Stereoisomerism
tandem catalysis
Vessels
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Summary:Fine‐tuning the conditions for a tandem reaction using a single catalyst in a single reaction vessel leads to carbohydrate building blocks displaying different patterns of protecting groups (see picture). This process greatly simplifies the access to oligomers, as illustrated by the rapid assembly of a trisaccharide.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200703437