Hybrid Particles of Polystyrene and Carboxymethyl Cellulose as Substrates for Copper Ions

• Published in: Langmuir 2005-08, Vol.21 (18), p.8515-8519
• Main Authors: Soares, K. V, Masini, J. C, Torresi, R. M, Carmona-Ribeiro, A. M, Petri, D. F. S
• Format: Article
• Language: English
• Subjects: Carboxymethylcellulose Sodium - chemistry; Cations - chemistry; Chemistry; Colloidal state and disperse state; Copper - chemistry; Exact sciences and technology; General and physical chemistry; Micelles. Thin films; Particle Size; Polystyrenes - chemistry; Surface physical chemistry
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/la050493r

The synthesis of hybrid particles was carried out by emulsion polymerization of styrene in complexes formed by carboxymethyl cellulose (CMC), a polyanion, and a cationic surfactant, cetyltrimethylammonium bromide (CTAB). CMC chains with variable molecular weights and degrees of substitution were tested. The polymerization condition chosen was that corresponding to CMC chains fully saturated with CTAB and to the onset of pure surfactant micelle formation, namely, at the critical aggregation concentration. The hybrid particles were characterized by zeta potential and light scattering measurements. The period of colloidal stability in the ionic strength of 2.0 mol L-1 NaCl was observed visually. Upon increasing the CMC chain length, the particle characteristics remained practically unchanged, but the colloid stability was increased. The increase in the CMC degree of substitution led to particles with more negative zeta potential values. The adsorption of copper ions (Cu2+) on the surface of hybrid particles could be described by the Langmuir model, as determined by potentiometric measurements. The increase in the mean zeta potential values and X-ray absorption near-edge spectra evidenced the immobilization of Cu2+ ions on the hybrid particles.