Planar Chiral Cyclic Ether:  Asymmetric Resolution and Chirality Transformation

Remarkably stable planar chirality was found in a nine-membered diallylic cyclic ether. Enantiomerically enriched ether was prepared by a kinetic resolution of a racemic one, which is valuable as a novel type of chiral building block.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2005-09, Vol.127 (35), p.12182-12183
Main Authors: Tomooka, Katsuhiko, Komine, Nobuyuki, Fujiki, Daisuke, Nakai, Takeshi, Yanagitsuru, Syun-ichi
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Chemical reactivity
Chemistry
Exact sciences and technology
General molecular conformation and symmetry
stereochemistry
Molecular properties and interactions with photons
Organic chemistry
Physics
Properties of molecules and molecular ions
Reactivity and mechanisms
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Description
Summary:Remarkably stable planar chirality was found in a nine-membered diallylic cyclic ether. Enantiomerically enriched ether was prepared by a kinetic resolution of a racemic one, which is valuable as a novel type of chiral building block.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja053347g