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Self-Encapsulation of Homogeneous Catalyst Species into Polymer Gel Leading to a Facile and Efficient Separation System of Amine Products in the Ru-Catalyzed Reduction of Carboxamides with Polymethylhydrosiloxane (PMHS)
A practical procedure for production of amines is offered by the ruthenium-catalyzed reduction of carboxamides with polymethylhydrosiloxane, in which encapsulation of the catalyst species into the formed insoluble siloxane resins contributes to the separation of both metallic and siloxane residues f...
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Published in: | Journal of the American Chemical Society 2005-09, Vol.127 (38), p.13150-13151 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | A practical procedure for production of amines is offered by the ruthenium-catalyzed reduction of carboxamides with polymethylhydrosiloxane, in which encapsulation of the catalyst species into the formed insoluble siloxane resins contributes to the separation of both metallic and siloxane residues from the product. |
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ISSN: | 0002-7863 1520-5126 |
DOI: | 10.1021/ja054453l |