Crystallization-Induced Diastereomer Transformations

This review covers the use of crystallization-induced diastereomer transformations from the first recorded case in 1846 through to the middle of 2005, with particular emphasis on progress in the last 25 years. In modern organic synthesis chromatographic separation of crude reaction products has larg...

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Bibliographic Details
Published in:Chemical reviews 2006-07, Vol.106 (7), p.2711-2733
Main Authors: Brands, Karel M. J, Davies, Antony J
Format: Article
Language:English
Subjects:
Amino Acids - chemistry
Chemical synthesis
Chemistry, Organic - methods
Crystallization
Molecular Structure
Organic chemistry
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Process engineering
Stereoisomerism
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Summary:This review covers the use of crystallization-induced diastereomer transformations from the first recorded case in 1846 through to the middle of 2005, with particular emphasis on progress in the last 25 years. In modern organic synthesis chromatographic separation of crude reaction products has largely supplanted the more time-consuming development of an efficient crystallization.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr0406864