Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations

The linear uranyl dication [UO2]2+ can be bound in one of two coordination sites in the ditopic Pacman-shaped pyrrolic macrocyle H4L. Incorporation of Mn2+, Fe2+, or Co2+ cations in the second donor compartment affords the first uranyl complexes with a transition-metal-functionalized oxo group.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2006-08, Vol.128 (30), p.9610-9611
Main Authors: Arnold, Polly L, Patel, Dipti, Blake, Alexander J, Wilson, Claire, Love, Jason B
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
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Summary:The linear uranyl dication [UO2]2+ can be bound in one of two coordination sites in the ditopic Pacman-shaped pyrrolic macrocyle H4L. Incorporation of Mn2+, Fe2+, or Co2+ cations in the second donor compartment affords the first uranyl complexes with a transition-metal-functionalized oxo group.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0634167