Regioselective aromatic C-H silylation of five-membered heteroarenes with fluorodisilanes catalyzed by iridium(I) complexes

The aromatic C-H silylation of five-membered heteroarenes with 1,2-di-tert-butyl-1,1,2,2-tetrafluorodisilane regioselectively proceeded at 120 degrees C in octane in the presence of a catalytic amount of iridium(I) complexes generated from 1/2[Ir(OMe)(COD)]2 and 2-tert-butyl-1,10-phenanthroline.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2005-10 (40), p.5065-5067
Main Authors: Ishiyama, Tatsuo, Sato, Kazuaki, Nishio, Yukihiro, Saiki, Takeaki, Miyaura, Norio
Format: Article
Language:English
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Summary:The aromatic C-H silylation of five-membered heteroarenes with 1,2-di-tert-butyl-1,1,2,2-tetrafluorodisilane regioselectively proceeded at 120 degrees C in octane in the presence of a catalytic amount of iridium(I) complexes generated from 1/2[Ir(OMe)(COD)]2 and 2-tert-butyl-1,10-phenanthroline.
ISSN:1359-7345
1364-548X
DOI:10.1039/b511171d