A Three-Dimensional Metal-Organic Framework with an Unprecedented Octahedral Building Unit

Unusual octahedral hexamers built up from triangular, corner‐linked cobalt trimers (see figure), form the basis of a novel three‐dimensional cobalt isophthalate obtained by a solvothermal route. This structure provides a new example of the concept of scale chemistry, in which an {Na6Co6O26} “super o...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2005-10, Vol.44 (40), p.6488-6491
Main Authors: Livage, Carine, Guillou, Nathalie, Chaigneau, Julienne, Rabu, Pierre, Drillon, Marc, Férey, Gérard
Format: Article
Language:English
Subjects:
carboxylate ligands
cobalt
metal-organic frameworks
solvothermal synthesis
supramolecular chemistry
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Summary:Unusual octahedral hexamers built up from triangular, corner‐linked cobalt trimers (see figure), form the basis of a novel three‐dimensional cobalt isophthalate obtained by a solvothermal route. This structure provides a new example of the concept of scale chemistry, in which an {Na6Co6O26} “super octahedron” is connected in a classical ReO3 architecture.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200502185