A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes

The new zinc compound N-cyclohexyl-2-(cyclohexylamino)troponiminate zinc methyl, [(Cy)2ATI]ZnMe, was synthesized and showed a superior reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to previously reported homogeneous zinc complexes.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2006-01 (32), p.3405-3407
Main Authors: Dochnahl, Maximilian, Pissarek, Jens-Wolfgang, Blechert, Siegfried, Löhnwitz, Karolin, Roesky, Peter W
Format: Article
Language:English
Subjects:
Alkenes - chemical synthesis
Alkenes - chemistry
Amination
Crystallography, X-Ray
Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Sensitivity and Specificity
Zinc - chemistry
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Summary:The new zinc compound N-cyclohexyl-2-(cyclohexylamino)troponiminate zinc methyl, [(Cy)2ATI]ZnMe, was synthesized and showed a superior reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to previously reported homogeneous zinc complexes.
ISSN:1359-7345
1364-548X
DOI:10.1039/b607597e