Ordered Liquid Aluminum at the Interface with Sapphire

Understanding the nature of solid-liquid interfaces is important for many processes of technological interest, such as solidification, liquid-phase epitaxial growth, wetting, liquid-phase joining, crystal growth, and lubrication. Recent studies have reported on indirect evidence of density fluctuati...

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Published in:Science (American Association for the Advancement of Science) 2005-10, Vol.310 (5748), p.661-663
Main Authors: Oh, S. H, Kauffmann, Y, Scheu, C, Kaplan, W. D, Růhle, M
Format: Article
Language:English
Subjects:
Aluminum
Analysis
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Crystals
Density
Electron microscopes
Evidence
Exact sciences and technology
Growth from melts
zone melting and refining
Heat
Laboratory Equipment
Liquids
Materials science
Methods of crystal growth
physics of crystal growth
Phase transitions
Physics
Solid-fluid interfaces
Solidification
Specific gravity
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Testing
Video Equipment
Videotape Recorders
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description Understanding the nature of solid-liquid interfaces is important for many processes of technological interest, such as solidification, liquid-phase epitaxial growth, wetting, liquid-phase joining, crystal growth, and lubrication. Recent studies have reported on indirect evidence of density fluctuations at solid-liquid interfaces on the basis of x-ray scattering methods that have been complemented by atomistic simulations. We provide evidence for ordering of liquid atoms adjacent to an interface with a crystal, based on real-time high-temperature observations of alumina-aluminum solid-liquid interfaces at the atomic-length scale. In addition, crystal growth of alumina into liquid aluminum, facilitated by interfacial transport of oxygen from the microscope column, was observed in situ with the use of high-resolution transmission electron microscopy.
doi_str_mv 10.1126/science.1118611
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subjects Aluminum
Analysis
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Crystals
Density
Electron microscopes
Evidence
Exact sciences and technology
Growth from melts
zone melting and refining
Heat
Laboratory Equipment
Liquids
Materials science
Methods of crystal growth
physics of crystal growth
Phase transitions
Physics
Solid-fluid interfaces
Solidification
Specific gravity
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Testing
Video Equipment
Videotape Recorders
title Ordered Liquid Aluminum at the Interface with Sapphire
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