The Importance of a β-β Bond for Long-Range Antiferromagnetic Coupling in Directly Linked Copper(II) and Silver(II) Diporphyrins

Interaction over a distance: Long‐range antiferromagnetic interactions between distant copper(II) and silver(II) ions are observed only for triply and singly linked diporphyrins with at least one β–β bond, which underscores the critical importance of this direct bond for antiferromagnetic coupling....

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Published in:Angewandte Chemie International Edition 2005-10, Vol.44 (42), p.6899-6901
Main Authors: Ikeue, Takahisa, Furukawa, Ko, Hata, Hiroshi, Aratani, Naoki, Shinokubo, Hiroshi, Kato, Tatsuhisa, Osuka, Atsuhiro
Format: Article
Language:English
Subjects:
copper
Copper - chemistry
Magnetics
magnetochemistry
metal-metal interactions
Models, Chemical
Molecular Structure
Organometallic Compounds - chemistry
porphyrinoids
Porphyrins - chemistry
silver
Silver - chemistry
Temperature
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cited_by cdi_FETCH-LOGICAL-c3813-69f7ffa6dbe9c9fc2d61580d82a221a0ec2d446dd83d7eac83a9c5af0deea6f03
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container_issue 42
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container_title Angewandte Chemie International Edition
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creator Ikeue, Takahisa
Furukawa, Ko
Hata, Hiroshi
Aratani, Naoki
Shinokubo, Hiroshi
Kato, Tatsuhisa
Osuka, Atsuhiro
description Interaction over a distance: Long‐range antiferromagnetic interactions between distant copper(II) and silver(II) ions are observed only for triply and singly linked diporphyrins with at least one β–β bond, which underscores the critical importance of this direct bond for antiferromagnetic coupling. These results can be qualitatively accounted for in terms of the spin distribution of copper(II) and silver(II) porphyrins (see picture).
doi_str_mv 10.1002/anie.200501943
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source Wiley-Blackwell Read & Publish Collection
subjects copper
Copper - chemistry
Magnetics
magnetochemistry
metal-metal interactions
Models, Chemical
Molecular Structure
Organometallic Compounds - chemistry
porphyrinoids
Porphyrins - chemistry
silver
Silver - chemistry
Temperature
title The Importance of a β-β Bond for Long-Range Antiferromagnetic Coupling in Directly Linked Copper(II) and Silver(II) Diporphyrins
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