Palladium-Catalyzed Cross-Coupling of Baylis−Hillman Acetate Adducts with Organosilanes

A cross-coupling reaction between acetates of Baylis−Hillman adducts and organosilanes is described. A nonconventional solvent poly(ethylene glycol) (PEG) is used as the reaction medium.

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Bibliographic Details
Published in:Journal of organic chemistry 2005-11, Vol.70 (23), p.9207-9210
Main Authors: Kabalka, George W, Dong, Gang, Venkataiah, Bollu, Chen, Chunlan
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
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Description
Summary:A cross-coupling reaction between acetates of Baylis−Hillman adducts and organosilanes is described. A nonconventional solvent poly(ethylene glycol) (PEG) is used as the reaction medium.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo051177k