Highly Efficient Aerobic Oxidation of Alcohols Using a Recoverable Catalyst: The Role of Mesoporous Channels of SBA-15 in Stabilizing Palladium Nanoparticles

Scaling down the activity: An efficient recyclable palladium‐based catalyst has been developed for the aerobic oxidation of alcohols (see scheme). The combination of a substituted bipyridyl ligand and ordered mesoporous channels (in SBA) causes a synergistic effect that results in enhanced activity,...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2006-07, Vol.45 (29), p.4776-4779
Main Authors: Karimi, Babak, Abedi, Sedigheh, Clark, James H., Budarin, Vitaly
Format: Article
Language:English
Subjects:
aerobic oxidation
alcohols
mesoporous materials
nanoparticles
palladium
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Summary:Scaling down the activity: An efficient recyclable palladium‐based catalyst has been developed for the aerobic oxidation of alcohols (see scheme). The combination of a substituted bipyridyl ligand and ordered mesoporous channels (in SBA) causes a synergistic effect that results in enhanced activity, the prevention of agglomeration of the palladium nanoparticles, and the generation of a durable catalyst.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200504359