Synthesis of Single-Crystalline CoP Nanowires by a One-Pot Metal−Organic Route

A simple one-pot method has been used to prepare uniform single-crystalline CoP nanowires with a high aspect ratio by the thermal-decomposition reaction of cobalt(II) acetylacetone with long-chain alkylphosphonic acid in the presence of hexadecylamine (HDA) and trioctylphosphine oxide (TOPO) at high...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2005-11, Vol.127 (46), p.16020-16021
Main Authors: Li, Yang, Malik, M. Azad, O'Brien, Paul
Format: Article
Language:English
Subjects:
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Nanoscale materials and structures: fabrication and characterization
Nanotubes
Physics
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Summary:A simple one-pot method has been used to prepare uniform single-crystalline CoP nanowires with a high aspect ratio by the thermal-decomposition reaction of cobalt(II) acetylacetone with long-chain alkylphosphonic acid in the presence of hexadecylamine (HDA) and trioctylphosphine oxide (TOPO) at high temperature. The crystal morphology of the resulting nanowires can be influenced by the ratio of HDA and TOPO.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja055963i