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Thermodynamics of an Incommensurate Quantum Crystal
We present a theory of the thermodynamics of an incommensurate quantum solid. The ground state of the solid is assumed to be an incommensurate crystal, with quantum zero-point vacancies and interstitials and thus a non-integer number of atoms per unit cell. We show that at low temperature T, the var...
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Published in: | Science (American Association for the Advancement of Science) 2005-11, Vol.310 (5751), p.1164-1166 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | We present a theory of the thermodynamics of an incommensurate quantum solid. The ground state of the solid is assumed to be an incommensurate crystal, with quantum zero-point vacancies and interstitials and thus a non-integer number of atoms per unit cell. We show that at low temperature T, the variation of the net vacancy concentration should be as T⁴ and that the first correction to the specific heat due to this varies as T⁷; these are quite consistent with experiments on solid helium-4. We also make some observations about the recent experimental reports of "supersolidity" in solid helium-4 that motivate a renewed interest in quantum crystals. |
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ISSN: | 0036-8075 1095-9203 |
DOI: | 10.1126/science.1118625 |