Unprecedented reactivity in the Morita-Baylis-Hillman reaction; intramolecular alpha-alkylation of enones using saturated alkyl halides

sp3 Hybridized electrophiles, never before used in the organomediated Morita-Baylis-Hillman reaction, now facilitate the formation of five- and six-membered enone cycloalkylation products.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2005-12 (46), p.5772-5774
Main Authors: Krafft, Marie E, Seibert, Kimberly A, Haxell, Thomas F N, Hirosawa, Chitaru
Format: Article
Language:English
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Description
Summary:sp3 Hybridized electrophiles, never before used in the organomediated Morita-Baylis-Hillman reaction, now facilitate the formation of five- and six-membered enone cycloalkylation products.
ISSN:1359-7345
1364-548X
DOI:10.1039/b512665g