Lead removal by polyacrylamide-bentonite and zeolite composites: Effect of phytic acid immobilization

• Published in: Journal of hazardous materials 2005-12, Vol.127 (1), p.163-171
• Main Authors: Ulusoy, Ulvi, Şimşek, Selçuk
• Format: Article
• Language: English
• Subjects: Acrylic Resins; Adsorbents; Adsorption; Aluminosilicates; Bentonite; Chemistry; Composite; Exact sciences and technology; General and physical chemistry; Lead; Lead - analysis; Phytate; Phytic Acid - pharmacokinetics; Surface physical chemistry; Zeolites
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2005.06.036

Polyacrylamide (PAA)-bentonite (B) and zeolite (Z) composites were prepared by direct polymerization of PAA in suspensions of B and Z. Phytate (Phy) immobilized onto the composites to obtain their Phy modifications. FT-IR and XRD were employed to characterize their structures. The sorption of Pb 2+ from various adsorption media onto the composites was then investigated. The reusability and storage characteristics of the adsorbents with and without Phy were also considered for Pb 2+ adsorption. All isotherms were L and H type of the Giles classification. The Phy adsorption capacities ( X M) of PAA-B and Z lower than those of bare B and Z due to their surface coverage by PAA. The Phy modification decreased the Pb 2+ adsorption capacities of B and PAA-B but ascended those of Z and PAA-Z. However, Phy significantly increased the Langmuir equilibrium constants ( K L) for all adsorbents. Ionic strength of the adsorption media was favorable for the adsorption capacity of PAA-B while not for that of PAA-Z. The chemical structure of the composites was not changed after five reuses and the storage foregoing. It is foreseen that the use of PAA-B and PAA-Z and their Phy modifications will provide practicality and effectiveness for Pb 2+ separation and removal procedures. The X M (mol kg −1) and K L (L mol −1) values for Pb 2+ adsorption from a model solution were 0.16 and 3625 for PAA-B, 0.18 and 5.1 × 10 5 for PAA-B-Phy, 0.28 and 13210 for PAA-Z and 1.65 and 2.0 × 10 5 for PAA-Z-Phy.