A single-bonded cationic terminal borylene complex

The cationic terminal borylene complex [(eta5-C5H5)(CO)2FeB(eta5-C5Me5)][AlCl4] has been isolated from the reaction of [(eta5-C5H5)(CO)2FeB(Cl)(eta1-C5Me5)] with AlCl3 and on the basis of X-ray crystallographic data, spectroscopic data and a DFT calculation it is concluded that the B-->Fe bond or...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2006-01 (36), p.3786-3787
Main Authors: Vidovic, Dragoslav, Findlater, Michael, Reeske, Gregor, Cowley, Alan H
Format: Article
Language:English
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Summary:The cationic terminal borylene complex [(eta5-C5H5)(CO)2FeB(eta5-C5Me5)][AlCl4] has been isolated from the reaction of [(eta5-C5H5)(CO)2FeB(Cl)(eta1-C5Me5)] with AlCl3 and on the basis of X-ray crystallographic data, spectroscopic data and a DFT calculation it is concluded that the B-->Fe bond order is one.
ISSN:1359-7345
1364-548X
DOI:10.1039/b609475a