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Bis[(2-pyridyl)(2-pyridylamino)methanolato]cobalt(III) perchlorate: a consequence of cobalt ion-assisted oxidative deamination of a tris(pyridyl)aminal ligand
The title compound, [Co(C11H10N3O)2]ClO4, designated [Co(L2)2]ClO4, was synthesized by reaction of CoII with two molar equivalents of (2‐pyridyl)bis(2‐pyridylamino)methane (L1) under ambient conditions, whereby the divalent metal ion was oxidized concomitantly with oxygenation and deamination of...
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| Published in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2005-12, Vol.61 (12), p.m497-m500 |
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| Main Authors: | , , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c5171-76c49eda7a15b1ff2714c333c199b22e265cb7e521397282b415257ce472b99d3 |
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| container_end_page | m500 |
| container_issue | 12 |
| container_start_page | m497 |
| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 61 |
| creator | Adams, Harry Shongwe, Musa S. Al-Bahri, Ibtisam Al-Busaidi, Eiman Morris, Michael J. |
| description | The title compound, [Co(C11H10N3O)2]ClO4, designated [Co(L2)2]ClO4, was synthesized by reaction of CoII with two molar equivalents of (2‐pyridyl)bis(2‐pyridylamino)methane (L1) under ambient conditions, whereby the divalent metal ion was oxidized concomitantly with oxygenation and deamination of the aminal polydentate ligand to generate the tridentate ligand anion (2‐pyridyl)(2‐pyridylamino)methanolate, L2−. In the X‐ray crystal structure of the complex cation, [Co(L2)2]+, the two L2− ligands are coordinated to the central cobalt(III) metal ion in a facial mode to afford a pseudo‐octahedral geometry. The four pyridyl N atoms constitute the equatorial plane on which the cobalt(III) ion lies; the methanolate O atoms occupy the axial positions. |
| doi_str_mv | 10.1107/S0108270105033913 |
| format | article |
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In the X‐ray crystal structure of the complex cation, [Co(L2)2]+, the two L2− ligands are coordinated to the central cobalt(III) metal ion in a facial mode to afford a pseudo‐octahedral geometry. The four pyridyl N atoms constitute the equatorial plane on which the cobalt(III) ion lies; the methanolate O atoms occupy the axial positions.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270105033913</identifier><identifier>PMID: 16330829</identifier><identifier>CODEN: ACSCEE</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: Munksgaard International Publishers</publisher><subject>Cobalt ; Condensed matter: structure, mechanical and thermal properties ; Crystal structure ; Exact sciences and technology ; Organic compounds ; Organometalloidal and organometallic compounds ; Oxidation ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Acta crystallographica. Section C, Crystal structure communications, 2005-12, Vol.61 (12), p.m497-m500</ispartof><rights>2006 INIST-CNRS</rights><rights>International Union of Crystallography, 2005</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5171-76c49eda7a15b1ff2714c333c199b22e265cb7e521397282b415257ce472b99d3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17323093$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16330829$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Adams, Harry</creatorcontrib><creatorcontrib>Shongwe, Musa S.</creatorcontrib><creatorcontrib>Al-Bahri, Ibtisam</creatorcontrib><creatorcontrib>Al-Busaidi, Eiman</creatorcontrib><creatorcontrib>Morris, Michael J.</creatorcontrib><title>Bis[(2-pyridyl)(2-pyridylamino)methanolato]cobalt(III) perchlorate: a consequence of cobalt ion-assisted oxidative deamination of a tris(pyridyl)aminal ligand</title><title>Acta crystallographica. Section C, Crystal structure communications</title><addtitle>Acta Cryst. C</addtitle><description>The title compound, [Co(C11H10N3O)2]ClO4, designated [Co(L2)2]ClO4, was synthesized by reaction of CoII with two molar equivalents of (2‐pyridyl)bis(2‐pyridylamino)methane (L1) under ambient conditions, whereby the divalent metal ion was oxidized concomitantly with oxygenation and deamination of the aminal polydentate ligand to generate the tridentate ligand anion (2‐pyridyl)(2‐pyridylamino)methanolate, L2−. In the X‐ray crystal structure of the complex cation, [Co(L2)2]+, the two L2− ligands are coordinated to the central cobalt(III) metal ion in a facial mode to afford a pseudo‐octahedral geometry. The four pyridyl N atoms constitute the equatorial plane on which the cobalt(III) ion lies; the methanolate O atoms occupy the axial positions.</description><subject>Cobalt</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Crystal structure</subject><subject>Exact sciences and technology</subject><subject>Organic compounds</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Oxidation</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFkd-K1DAUxoMo7rj6AN5IEVxmLqo5Sdu03s0O7jqwqOwqi4iENE3drGkzJh3dvpIwLzFPZmpHB_RiIeTf-X1fcvgQegz4OQBmLy4w4JywMKeY0gLoHTSBDOM4ZWlxF02GcjzUD9AD768xxoQQeh8dQEZpUBYT9PNY-09TEq96p6vtpjezP4febDei0a2dbTeN6q5Ea4ebzn6WthSmmy6Xy1m0Uk5eGetEp15GIpK29erbWrVSRbaORjLSto2F99p3qorsja5Ep7-rqFKDf9jbdoBF1Dntt5vp_i-_6yYy-otoq4foXi2MV4926yH6cPLq_eJ1fPb2dLmYn8UyBQYxy2RSqEowAWkJdU0YJJJSKqEoSkIUyVJZMpUSoAUjOSkTSEnKpEoYKYuioofoaPRdORta8R1vtJfKGNEqu_Y8y_MwAN8KkhwykuRZAJ_-A17btQudBQZTSBLGkgDBCElnvXeq5iunG-F6DpgPcfP_4g6aJzvjddmoaq_Y5RuAZztAeClM7UQrtd9zjBKKi8EoH7kf2qj-9pf5_OPiZA6QQZDGo3SI9-avVLivPGOUpfzyzSk_T84v2LvkkgP9BYrT1gU</recordid><startdate>200512</startdate><enddate>200512</enddate><creator>Adams, Harry</creator><creator>Shongwe, Musa S.</creator><creator>Al-Bahri, Ibtisam</creator><creator>Al-Busaidi, Eiman</creator><creator>Morris, Michael J.</creator><general>Munksgaard International Publishers</general><general>Blackwell</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>200512</creationdate><title>Bis[(2-pyridyl)(2-pyridylamino)methanolato]cobalt(III) perchlorate: a consequence of cobalt ion-assisted oxidative deamination of a tris(pyridyl)aminal ligand</title><author>Adams, Harry ; Shongwe, Musa S. ; Al-Bahri, Ibtisam ; Al-Busaidi, Eiman ; Morris, Michael J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5171-76c49eda7a15b1ff2714c333c199b22e265cb7e521397282b415257ce472b99d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Cobalt</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Crystal structure</topic><topic>Exact sciences and technology</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Oxidation</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adams, Harry</creatorcontrib><creatorcontrib>Shongwe, Musa S.</creatorcontrib><creatorcontrib>Al-Bahri, Ibtisam</creatorcontrib><creatorcontrib>Al-Busaidi, Eiman</creatorcontrib><creatorcontrib>Morris, Michael J.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adams, Harry</au><au>Shongwe, Musa S.</au><au>Al-Bahri, Ibtisam</au><au>Al-Busaidi, Eiman</au><au>Morris, Michael J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bis[(2-pyridyl)(2-pyridylamino)methanolato]cobalt(III) perchlorate: a consequence of cobalt ion-assisted oxidative deamination of a tris(pyridyl)aminal ligand</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2005-12</date><risdate>2005</risdate><volume>61</volume><issue>12</issue><spage>m497</spage><epage>m500</epage><pages>m497-m500</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><coden>ACSCEE</coden><abstract>The title compound, [Co(C11H10N3O)2]ClO4, designated [Co(L2)2]ClO4, was synthesized by reaction of CoII with two molar equivalents of (2‐pyridyl)bis(2‐pyridylamino)methane (L1) under ambient conditions, whereby the divalent metal ion was oxidized concomitantly with oxygenation and deamination of the aminal polydentate ligand to generate the tridentate ligand anion (2‐pyridyl)(2‐pyridylamino)methanolate, L2−. In the X‐ray crystal structure of the complex cation, [Co(L2)2]+, the two L2− ligands are coordinated to the central cobalt(III) metal ion in a facial mode to afford a pseudo‐octahedral geometry. The four pyridyl N atoms constitute the equatorial plane on which the cobalt(III) ion lies; the methanolate O atoms occupy the axial positions.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Munksgaard International Publishers</pub><pmid>16330829</pmid><doi>10.1107/S0108270105033913</doi><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2005-12, Vol.61 (12), p.m497-m500 |
| issn | 0108-2701 1600-5759 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_68868810 |
| source | Wiley-Blackwell Read & Publish Collection; Alma/SFX Local Collection |
| subjects | Cobalt Condensed matter: structure, mechanical and thermal properties Crystal structure Exact sciences and technology Organic compounds Organometalloidal and organometallic compounds Oxidation Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Bis[(2-pyridyl)(2-pyridylamino)methanolato]cobalt(III) perchlorate: a consequence of cobalt ion-assisted oxidative deamination of a tris(pyridyl)aminal ligand |
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