Secondary Bonding Interactions Observed in Two Arsenic Thiolate Complexes

Treatment of N-(2-mercaptoethyl)-1,8-naphthalimide (HL) with stoichiometric amounts of AsCl3 and base affords AsL 2Cl and AsL 3 complexes stabilized in part by secondary As···O bonding interactions.

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Bibliographic Details
Published in:Inorganic chemistry 2005-12, Vol.44 (26), p.9634-9636
Main Authors: Carter, Timothy G, Healey, Elisabeth Rather, Pitt, Melanie A, Johnson, Darren W
Format: Article
Language:English
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Summary:Treatment of N-(2-mercaptoethyl)-1,8-naphthalimide (HL) with stoichiometric amounts of AsCl3 and base affords AsL 2Cl and AsL 3 complexes stabilized in part by secondary As···O bonding interactions.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic051522o