[Zn(n)(polyox)(pmtz)n]: the first polyoxalate-containing coordination polymer from an unforeseen chemical rearrangement of 5-pyrimidyl-tetrazole under hydrothermal conditions

The compound [Zn(2)(polyox)(pmtz)(2)], which has been prepared by the hydrothermal reaction of ZnCl(2) and Napmtz (5-pyrimidyl-tetrazolate), exhibits a unique 2D network with (6,3) topology, in which Zn(II) ions are connected by pmtz- and polyoxalate-bridging ligands (generated in situ from the brea...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2006-10 (39), p.4140-4142
Main Authors: Rodríguez-Diéguez, A, Colacio, E
Format: Article
Language:English
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Summary:The compound [Zn(2)(polyox)(pmtz)(2)], which has been prepared by the hydrothermal reaction of ZnCl(2) and Napmtz (5-pyrimidyl-tetrazolate), exhibits a unique 2D network with (6,3) topology, in which Zn(II) ions are connected by pmtz- and polyoxalate-bridging ligands (generated in situ from the breaking of the pmzt(-) ligand). This is the first structural report on a polyoxalate species.
ISSN:1359-7345
1364-548X
DOI:10.1039/b608403f