Supramolecular Chirogenesis in Bis-porphyrins:  Interaction with Chiral Acids and Application for the Absolute Configuration Assignment

A new supramolecular chirogenic system on the basis of bis(free base porphyrin) and various enantiopure acids, which can be effectively applied for the chirality sensing purposes, is reported. The temperature and solvent are found to be key factors controlling the chirality transfer process in these...

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Published in:Organic letters 2007-02, Vol.9 (3), p.433-435
Main Authors: Bhyrappa, Puttaiah, Borovkov, Victor V, Inoue, Yoshihisa
Format: Article
Language:English
Subjects:
Carboxylic Acids - chemistry
Molecular Structure
Porphyrins - chemistry
Solvents - chemistry
Spectrophotometry, Ultraviolet
Stereoisomerism
Temperature
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description A new supramolecular chirogenic system on the basis of bis(free base porphyrin) and various enantiopure acids, which can be effectively applied for the chirality sensing purposes, is reported. The temperature and solvent are found to be key factors controlling the chirality transfer process in these assemblies.
doi_str_mv 10.1021/ol062776w
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ispartof Organic letters, 2007-02, Vol.9 (3), p.433-435
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Carboxylic Acids - chemistry
Molecular Structure
Porphyrins - chemistry
Solvents - chemistry
Spectrophotometry, Ultraviolet
Stereoisomerism
Temperature
title Supramolecular Chirogenesis in Bis-porphyrins:  Interaction with Chiral Acids and Application for the Absolute Configuration Assignment
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