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One-Step Heterylation at the Upper Rim of Calix[4]arene with 1,2,4-Triazin-5(2H)-ones

A convenient way to modify calix[4]arenes based on the direct C−C coupling reaction of their phenol moiety with 1,2,4-triazines has been advanced, and the ability of modified calixarenes to provide transport of La3+ and Ga3+ cations through organic membranes has been examined.

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Bibliographic Details
Published in:Journal of organic chemistry 2006-10, Vol.71 (21), p.8272-8275
Main Authors: Beresnev, Dmitry G, Itsikson, Nadezhda A, Chupakhin, Oleg N, Charushin, Valery N, Kodess, Mikhail I, Butakov, Alexander I, Rusinov, Gennady L, Morzherin, Yuri Yu, Konovalov, Alexander I, Antipin, Igor S
Format: Article
Language:English
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Summary:A convenient way to modify calix[4]arenes based on the direct C−C coupling reaction of their phenol moiety with 1,2,4-triazines has been advanced, and the ability of modified calixarenes to provide transport of La3+ and Ga3+ cations through organic membranes has been examined.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo061069d