High-Capacity Hydrogen and Nitric Oxide Adsorption and Storage in a Metal−Organic Framework

Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal−organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g-1, 2.27 wt %) at 1 bar and 18 mmol per g (36.28 mg...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2007-02, Vol.129 (5), p.1203-1209
Main Authors: Xiao, Bo, Wheatley, Paul S, Zhao, Xuebo, Fletcher, Ashleigh J, Fox, Sarah, Rossi, Adriano G, Megson, Ian L, Bordiga, S, Regli, L, Thomas, K. Mark, Morris, Russell E
Format: Article
Language:English
Subjects:
Adsorption
Biotechnology
Hydrogen - chemistry
Luminescence
Manufactured Materials
Metals - chemistry
Nitric Oxide - chemistry
Platelet Aggregation
Porosity
Spectrophotometry, Infrared
Stress, Mechanical
Surface Properties
Temperature
Thermogravimetry
Time Factors
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Summary:Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal−organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g-1, 2.27 wt %) at 1 bar and 18 mmol per g (36.28 mg g-1, 3.6 wt %) at 10 bar. Adsorption of D2 at 1 bar (77 K) is between 1.09 (at 1 bar) and 1.20(at
ISSN:0002-7863
1520-5126
DOI:10.1021/ja066098k