Catalytic Promiscuity in Biomimetic Systems:  Catecholase-like Activity, Phosphatase-like Activity, and Hydrolytic DNA Cleavage Promoted by a New Dicopper(II) Hydroxo-Bridged Complex

Presented in this Communication are the structure, physicochemical properties, and catalytic promiscuity of a new dinuclear CuII(μ-OH)CuII complex containing a novel N,O-donor symmetric dinucleating ligand.

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Bibliographic Details
Published in:Inorganic chemistry 2007-01, Vol.46 (2), p.348-350
Main Authors: Rey, Nicolás A., Neves, Ademir, Bortoluzzi, Adailton J., Pich, Claus T., Terenzi, Hernán
Format: Article
Language:English
Subjects:
Catalysis
Catechols - metabolism
Copper - metabolism
DNA - metabolism
Hydrolysis
Models, Molecular
Molecular Mimicry
Phosphoric Monoester Hydrolases - metabolism
Spectrophotometry, Ultraviolet
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Description
Summary:Presented in this Communication are the structure, physicochemical properties, and catalytic promiscuity of a new dinuclear CuII(μ-OH)CuII complex containing a novel N,O-donor symmetric dinucleating ligand.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic0613107