Catalytic Promiscuity in Biomimetic Systems:  Catecholase-like Activity, Phosphatase-like Activity, and Hydrolytic DNA Cleavage Promoted by a New Dicopper(II) Hydroxo-Bridged Complex

Presented in this Communication are the structure, physicochemical properties, and catalytic promiscuity of a new dinuclear CuII(μ-OH)CuII complex containing a novel N,O-donor symmetric dinucleating ligand.

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Published in:Inorganic chemistry 2007-01, Vol.46 (2), p.348-350
Main Authors: Rey, Nicolás A., Neves, Ademir, Bortoluzzi, Adailton J., Pich, Claus T., Terenzi, Hernán
Format: Article
Language:English
Subjects:
Catalysis
Catechols - metabolism
Copper - metabolism
DNA - metabolism
Hydrolysis
Models, Molecular
Molecular Mimicry
Phosphoric Monoester Hydrolases - metabolism
Spectrophotometry, Ultraviolet
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cited_by cdi_FETCH-LOGICAL-a351t-9b608f9ae71f3190a6d3d50e782e8efa19a3fd3620411e4d99971cf293efebb73
cites cdi_FETCH-LOGICAL-a351t-9b608f9ae71f3190a6d3d50e782e8efa19a3fd3620411e4d99971cf293efebb73
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container_start_page 348
container_title Inorganic chemistry
container_volume 46
creator Rey, Nicolás A.
Neves, Ademir
Bortoluzzi, Adailton J.
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description Presented in this Communication are the structure, physicochemical properties, and catalytic promiscuity of a new dinuclear CuII(μ-OH)CuII complex containing a novel N,O-donor symmetric dinucleating ligand.
doi_str_mv 10.1021/ic0613107
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Catalysis
Catechols - metabolism
Copper - metabolism
DNA - metabolism
Hydrolysis
Models, Molecular
Molecular Mimicry
Phosphoric Monoester Hydrolases - metabolism
Spectrophotometry, Ultraviolet
title Catalytic Promiscuity in Biomimetic Systems:  Catecholase-like Activity, Phosphatase-like Activity, and Hydrolytic DNA Cleavage Promoted by a New Dicopper(II) Hydroxo-Bridged Complex
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