Preparation of fused polycyclic vinylcyclopropanes via radical cascade reactions

Radical cascades employing (dichloromethyl)dimethylsilyl ethers as both a point of radical initiation and termination, allow efficient entry to fused polycyclic cyclopropanes, and are also suitable for the design of other radical processes terminated by beta-elimination of chloride.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2007-03 (9), p.936-938
Main Authors: Maddess, Matthew L, Mainetti, Emily, Harrak, Youssef, Brancour, Célia, Devin, Priscille, Dhimane, Anne-Lise, Fensterbank, Louis, Malacria, Max
Format: Article
Language:English
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Summary:Radical cascades employing (dichloromethyl)dimethylsilyl ethers as both a point of radical initiation and termination, allow efficient entry to fused polycyclic cyclopropanes, and are also suitable for the design of other radical processes terminated by beta-elimination of chloride.
ISSN:1359-7345
1364-548X
DOI:10.1039/b618156b