Bi-3H-diazirin-3-yls as Precursors of Highly Strained Cycloalkynes

No reagents and very mild conditions are required for the transformation of isolable precursors 3 into highly strained cycloalkynes 4 (cycloheptyne, cyclohexyne, norbornyne), which can be trapped by cycloaddition reactions.

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Published in:Angewandte Chemie International Edition 2005-12, Vol.45 (2), p.309-311
Main Authors: Al-Omari, Mohammad, Banert, Klaus, Hagedorn, Manfred
Format: Article
Language:English
Subjects:
cycloaddition
cycloalkynes
reactive intermediates
spiro compounds
strained molecules
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container_title Angewandte Chemie International Edition
container_volume 45
creator Al-Omari, Mohammad
Banert, Klaus
Hagedorn, Manfred
description No reagents and very mild conditions are required for the transformation of isolable precursors 3 into highly strained cycloalkynes 4 (cycloheptyne, cyclohexyne, norbornyne), which can be trapped by cycloaddition reactions.
doi_str_mv 10.1002/anie.200503124
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source Wiley-Blackwell Read & Publish Collection
subjects cycloaddition
cycloalkynes
reactive intermediates
spiro compounds
strained molecules
title Bi-3H-diazirin-3-yls as Precursors of Highly Strained Cycloalkynes
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