Electrically-Driven Chiroptical Switches Based on Axially Dissymmetric 1,1‘-Binaphthyl and Electrochromic Viologens:  Synthesis and Optical Properties

A novel redox type of chiral molecular switch based on axially dissymmetric 1,1‘-binaphthyl and electrochromic 4,4‘-bipyridinium exhibits drastic changes in absorption and circular dichroism spectra upon electrochemical redox reaction and is fully characterized for the electrically driven chiroptica...

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Published in:Organic letters 2007-12, Vol.9 (26), p.5393-5396
Main Authors: Deng, Jian, Song, Naiheng, Zhou, Qifeng, Su, Zhixing
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Language:English
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description A novel redox type of chiral molecular switch based on axially dissymmetric 1,1‘-binaphthyl and electrochromic 4,4‘-bipyridinium exhibits drastic changes in absorption and circular dichroism spectra upon electrochemical redox reaction and is fully characterized for the electrically driven chiroptical switching properties.
doi_str_mv 10.1021/ol701822u
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title Electrically-Driven Chiroptical Switches Based on Axially Dissymmetric 1,1‘-Binaphthyl and Electrochromic Viologens:  Synthesis and Optical Properties
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