Rhenium-Catalyzed Hydroamidation of Unactivated Terminal Alkynes:  Synthesis of (E)-Enamides

Reactions of cyclic amides with unactivated terminal alkynes in the presence of a catalytic amount of a rhenium complex provided (E)-enamides in high regio- and stereoselectivity (E:Z = >99:

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Bibliographic Details
Published in:Organic letters 2007-12, Vol.9 (26), p.5609-5611
Main Authors: Yudha S, Salprima, Kuninobu, Yoichiro, Takai, Kazuhiko
Format: Article
Language:English
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Summary:Reactions of cyclic amides with unactivated terminal alkynes in the presence of a catalytic amount of a rhenium complex provided (E)-enamides in high regio- and stereoselectivity (E:Z = >99:
ISSN:1523-7060
1523-7052
DOI:10.1021/ol702564e