Unusual parallel and inclined interlocking modes in polyrotaxane-like metal-organic frameworks

We describe here two unusual polyrotaxane-like metal-organic frameworks of [Co2(1,3-bix)2(bpea)2] and [Cd4(1,4-bix)4(bpea)4] x 4H2O , where both species contain loops and rods that are interlaced in a highly rare "parallel" fashion in , but, uniquely, in an "inclined" fashion in...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2008-05 (19), p.2233-2235
Main Authors: Yang, Jin, Ma, Jian-Fang, Batten, Stuart R, Su, Zhong-Min
Format: Article
Language:English
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Summary:We describe here two unusual polyrotaxane-like metal-organic frameworks of [Co2(1,3-bix)2(bpea)2] and [Cd4(1,4-bix)4(bpea)4] x 4H2O , where both species contain loops and rods that are interlaced in a highly rare "parallel" fashion in , but, uniquely, in an "inclined" fashion in .
ISSN:1359-7345
1364-548X
DOI:10.1039/b800199e