Synthesis, Structure, and Metal Complexation Behavior of a New Type of Functionalized Chiral Phenanthroline Derivative

SmI2 serves as an effective promoter for the coupling of 1,10-phenanthroline with an epoxide to generate a new class of chiral, functionalized ligands that readily form complexes with metals. Structural studies of the resulting phenanthroline derivative and two of its metal complexes are reported.

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Bibliographic Details
Published in:Journal of organic chemistry 2008-05, Vol.73 (10), p.3911-3914
Main Authors: Plummer, Jacob M, Weitgenant, Jeremy A, Noll, Bruce C, Lauher, Joseph W, Wiest, Olaf, Helquist, Paul
Format: Article
Language:English
Subjects:
Chemistry
Copper - chemistry
Crystallography, X-Ray
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Hydrogen Bonding
Ligands
Models, Molecular
Molecular Structure
Organic chemistry
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Phenanthrolines - chemical synthesis
Phenanthrolines - chemistry
Preparations and properties
Samarium - chemistry
Stereoisomerism
Zinc - chemistry
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Description
Summary:SmI2 serves as an effective promoter for the coupling of 1,10-phenanthroline with an epoxide to generate a new class of chiral, functionalized ligands that readily form complexes with metals. Structural studies of the resulting phenanthroline derivative and two of its metal complexes are reported.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo702566m