Novel Ascorbic Acid Based Ionic Liquids for the In Situ Synthesis of Quasi-Spherical and Anisotropic Gold Nanostructures in Aqueous Medium

• Published in: Chemistry : a European journal 2008-06, Vol.14 (18), p.5528-5537
• Main Authors: Dinda, Enakshi, Si, Satyabrata, Kotal, Atanu, Mandal, Tarun K.
• Format: Article
• Language: English
• Subjects: anisotropic; ascorbic acid; Ascorbic Acid - chemistry; Calorimetry, Differential Scanning; Gold - chemistry; gold nanostructures; ionic liquids; Magnetic Resonance Spectroscopy; Metal Nanoparticles; Microscopy, Electron, Transmission; Oxidation-Reduction; redox chemistry; Spectrophotometry, Ultraviolet; Spectroscopy, Fourier Transform Infrared; Water - chemistry
• ISSN: 0947-6539; 1521-3765
• DOI: 10.1002/chem.200800006

A series of newly designed ascorbic acid based room temperature ionic liquids were successfully used to prepare quasi‐spherical and anisotropic gold nanostructures in an aqueous medium at ambient temperature. The synthesis of these room temperature ionic liquids involves, first, the preparation of a 1‐alkyl (such as methyl, ethyl, butyl, hexyl, octyl, and decyl) derivative of 3‐methylimidazolium hydroxide followed by the neutralization of the derivatised product with ascorbic acid. These ionic liquids show significantly better thermal stability and their glass transition temperature (Tg) decreases with increasing alkyl chain length. The ascorbate counter anion of these ionic liquids acts as a reducing agent for HAuCl4 to produce metallic gold and the alkylated imidazolium counter cation acts as a capping/shape‐directing agent. It has been found that the nature of the ionic liquids and the mole ratio of ionic liquid to HAuCl4 has a significant effect on the morphology of the formed gold nanostructures. If an equimolar mixture of ionic liquid and HAuCl4 is used, predominantly anisotropic gold nanostructures are formed and by varying the alkyl chain length attached to imidazolium cation of the ionic liquids, various particle morphologies can formed, such as quasispherical, raspberry‐like, flakes or dendritic. A probable formation mechanism for such anisotropic gold nanostructures has been proposed, which is based on the results of some control experiments. Strike gold: A series of newly designed ascorbic acid based, room‐temperature ionic liquids were synthesized and used to prepare quasi‐spherical and anisotropic gold nanostructures in aqueous medium (see figure).