D+−π−A− Charge-Transfer Molecules Based on Tricyanoquinodimethane and Diphosphine Metal Complexes

A new family of D+−π−A− chromophores in which the donor group is an organometallic complex and the acceptor group a tricyanoquinodimethane moiety has been synthesized by the reaction of diphosphinomethanide transition-metal complexes and 7,7′,8,8′-tetracyanoquinodimethane.

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Bibliographic Details
Published in:Inorganic chemistry 2008-07, Vol.47 (13), p.5540-5542
Main Authors: Ruiz, Javier, Antón, Maria J, Vivanco, Marilín, Mosquera, Marta E. G, Quesada, Roberto
Format: Article
Language:English
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Summary:A new family of D+−π−A− chromophores in which the donor group is an organometallic complex and the acceptor group a tricyanoquinodimethane moiety has been synthesized by the reaction of diphosphinomethanide transition-metal complexes and 7,7′,8,8′-tetracyanoquinodimethane.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic8008333